No stranger to the Hot 100, Jessica first caused our collective blood pressure to rise with her role as a distractingly sexy preacher’s daughter on the family-friendly series 7th Heaven. She’s since kicked off her goody two-shoes and become a major movie star—blame the six seconds of Jessica wearing undies in I Now Pronounce You Chuck and Larry for its improbable $120 million box office haul. Now she’s set to star in what sounds like the greatest movie ever, Nailed, in which “a freak accident turns a small-town woman into a sexually adventurous bombshell.”